DELIGNIFICATION OF VEGETABLE RAW MATERIAL CATALYTIC BY HYDROGEN PEROXIDE AND PEROXI-COMBINATIONS (REVIEW)
نویسندگان
چکیده
منابع مشابه
Delignification of rye straw using hydrogen peroxide
Alkaline peroxide delignification of rye straw has been first investigated in this paper. The results showed that treatment of dewaxed and water-extracted rye straw with 2% H2O2 at pH 11.5 for 12 h at 20, 30, 40, 50, 60, and 70°C resulted in a dissolution of 52.7, 75.7, 81.8, 83.1, 85.8, and 87.8% of the original lignin, and 44.2, 52.5, 70.0, 70.0, 71.3, and 71.9% of the original hemicelluloses...
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The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free e...
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The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free e...
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Neutron diffraction profiles for cellulose from different sources were compared before and after alkaline hydrogen peroxide (AHP) treatment. It was found that AHP treatment did not cause detectable changes in the structure of highly polymerized cellulose. In measurements on wheat straw, peaks were observed at the angles characteristic of pure cellulose. Changes, with AHP treatment, of the inten...
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Hydrogen peroxide (H2O2) is a strong oxidizing agent. High concentration H2O2 or High Test Peroxide (HTP) has been used extensively in the past in propulsion applications as mono and bipropellant. At low temperature, HTP can be catalytically decomposed to water and oxygen. Drawbacks to this approach include catalyst poisoning due to the presence of stabilizers in HTP, and susceptibility of the ...
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ژورنال
عنوان ژورنال: chemistry of plant raw material
سال: 2020
ISSN: 1029-5143,1029-5151
DOI: 10.14258/jcprm.2020048119